"When It's Cold I'd Like to Die" by Moby in The Sopranos (S6 E2)

Shameless taken by Stranger Things, over and over, this all-timer from Moby gives us a stunning moment where Tony, stuck in his dream/coma state as Kevin Finnerty, is deciding whether to pick up the phone (continue to live) or just resign to death's cold embrace.

Peak moment from a peak show. That being said, so many other classics available

Singing "Dirty Work"

Brining "Glad Tidings" from New York

and of course, the incredibly well done interplay between "Every Breath You Take" and the "Theme From Peter Gunn".